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Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1450-1459 doi: 10.1007/s11705-023-2310-3

摘要: Membrane technology is ideal for removing aqueous humic acid, but humic acid deposits cause membrane fouling, a significant challenge that limits its application. Herein, this work proposed an alternative approach to the controllably magnetically induced magneto-hybrid polyoxometalate (magneto-HPOM) nanocomposite migration toward the polyethersulfone (PES) membrane surface under a magnetic field to enhance the self-cleaning and antifouling functionalities of the membrane. Before incorporating magneto-HPOM nanocomposite into the PES casting solution, functionalized magnetite nanoparticles (F-MNP) were first coated with HPOM photocatalyst to fabricate a magneto-HPOM-PES membrane. It was shown that the apparent impacts of this novel magneto-HPOM-PES membrane on the hydrophilic behavior and photocatalytic properties of the magneto-HPOM nanocomposite improve the hydrophilicity, separation performance, antifouling and self-cleaning properties of the membrane compared with neat PES membrane. Furthermore, after exposure to ultraviolet light, the magneto-HPOM-PES membrane can be recovered after three cycles with a flux recovery ratio of 107.95%, 100.06%, and 95.56%, which is attributed to the temporal super hydrophilicity effect. Meanwhile, the magneto-HPOM-PES membrane could efficiently maintain 100% humic acid rejection for the first and second cycles and 99.81% for the third cycle. This study revealed a novel approach to fabricating membranes with high antifouling and self-cleaning properties for water treatment.

关键词: magneto-hybrid polyoxometalate nanocomposite     composite membrane     antifouling     self-cleaning     magnetic and photocatalytic responsiveness    

Preparation and characterization of ZnO/ZnS hybrid photocatalysts via microwave-hydrothermal method

ZHAO Jinglian, WANG Xinping, ZHAO Liang

《环境科学与工程前沿(英文)》 2008年 第2卷 第4期   页码 415-420 doi: 10.1007/s11783-008-0056-2

摘要: The photocatalytic performance of ZnO/ZnS hybrid nanocomposite was largely higher than that of the mere ZnO or ZnS nanoparticles, but the complicated procedure and misdistribution of final products limited its large-scale productions. The exploration of a novel synthesis route of ZnO/ZnS hybrid photocatalysts with high catalytic performance is becoming a crucial step for the large-scale application of ZnO/ZnS hybrid photocatalytic technique. Preparation and characterization of nanosized ZnO/ZnS hybrid photocatalysts were studied in this paper. The photocatalysts were obtained via microwave-hydrothermal crystallization with the help of sodium citrate. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), particle size distribution (PSD), and Fourier transformed infrared spectroscopy (FT-IR). The results indicated that so-synthesized ZnO/ZnS samples consisted of the high pure cubic (sphalerite) ZnS and hexagonal ZnO nanocrystallines with a narrow particle size distribution. The possible formation mechanisms of ZnO/ZnS nanocrystallines were mainly attributed to the superficially protective effect of citrate. The photocatalytic experiments demonstrated that the ZnO/ZnS photocatalysts exhibited a higher catalytic activity for the degradation of acid fuchsine than other monocomponents.

关键词: large-scale     hexagonal     misdistribution     characterization     nanocomposite    

Vibration control of a structure using Magneto-Rheological grease damper

Shinya SUGIYAMA, Tomoki SAKURAI, Shin MORISHITA

《机械工程前沿(英文)》 2013年 第8卷 第3期   页码 261-267 doi: 10.1007/s11465-013-0268-4

摘要:

This paper describes an application study of Magneto-Rheological (MR) grease damper to a structure with three stories. MR fluid is known as one of successful smart materials whose rheological properties can be varied by magnetic field strength, and has been applied to various kinds of device such as dampers, clutches, engine mounts, etc. However, ferromagnetic particles dispersed in MR fluid settle out of the suspension after a certain interval due to the density difference between the particles and their career fluid. To overcome this defect, we have developed a new type of controllable working fluid using grease as the career of magnetic particles. Network of thickener in grease is expected to hold the magnetic particles and prevent them from settled down. No or little sedimentation was observed in MR grease whose characteristics could be controlled by the magnetic field strength. MR grease was introduced into a cylindrical damper and its performance was studied. As a result, it was confirmed that the damping force of MR grease damper could be controlled by the applied electric current to the coil in the cylinder of damper. Furthermore, vibration response of a three-story model structure equipped with MR grease damper was investigated experimentally, and it was shown that MR grease damper worked effectively as a semi-active damper.

关键词: vibration control     damper     smart material     Magneto-Rheological (MR) grease     MR fluid    

Effect of magneto rheological damper on tool vibration during hard turning

P. Sam PAUL, A. S. VARADARAJAN

《机械工程前沿(英文)》 2012年 第7卷 第4期   页码 410-416 doi: 10.1007/s11465-012-0341-4

摘要:

Recently, the concept of hard turning has gained considerable attention in metal cutting as it can apparently replace the traditional process cycle of turning, heat treating, and finish grinding for assembly of hard wear resistant steel parts. The present investigation aims at developing a magneto rheological (MR) fluid damper for suppressing tool vibration and promoting better cutting performance during hard turning. The magneto rheological Fluid acts as a viscoelastic spring with non-linear vibration characteristics that are controlled by the composition of the magneto rheological fluid, the shape of the plunger and the electric parameters of the magnetizing field. Cutting experiments were conducted to arrive at a set of electrical, compositional and shape parameters that can suppress tool vibration and promote better cutting performance during turning of AISI 4340 steel of 46 HRC with minimal fluid application using hard metal insert with sculptured rake face. It was observed that the use of MR fluid damper reduces tool vibration and improves the cutting performance effectively. Also commercialization of this idea holds promise to the metal cutting industry.

关键词: tool vibration     magneto rheological damper     hard turning     surface finish     tool wear    

Polymer nanocomposites for microactuation and magneto-electric transduction

Kaori YUSE, Benoit GUIFFARD, Rabah BELOUADAH, Lionel PETIT, Laurence SEVEYRAT, Daniel GUYOMAR

《机械工程前沿(英文)》 2009年 第4卷 第3期   页码 350-354 doi: 10.1007/s11465-009-0056-3

摘要: In the last decade, electroactive polymers have attracted much attention especially because of their very actuating capabilities. Large strain is experimentally observed, but under quite high electrical field, which can be a severe drawback for actuating applications. First part of the present paper is concerned with the reduction of applied field onto electroactive polymer films to get a given strain level. Polyurethane (PU) films filled with carbon black (CB) nanoparticles exhibit relatively high strain level under a field of only 12.5 kV/mm. The simple easy-to-make method solution cast method was applied. Even though the generated stress level is still quite low, the present work shows high strain level under quite low field appliance by easy manufacturing, lightweight, and flexible polymer film. Besides, another interest of the present paper is in magneto-elasto-electric effect of a polymer film filled with some magnetic nano particles. Films filled with nonpiezoelectric but with magnetite particles has still short history. With the use of magneto materials, a large magnetic DC bias field is generally required, and it causes big problem on application. The films filled with some magnetite nanoparticles (Fe3O4 and Nickel) are fabricated then examined. It is clearly demonstrated that our films do not require any DC bias. Although linear polarization value is relatively small, the first step of the studies on magnetite nano-filled film is presented.

关键词: electroactive polymers     carbon filling     actuator     nanocarbon     electromechanical coupling     dielectric polymer actuators     polymer actuators     microactuation     magneto-electric effect    

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

《环境科学与工程前沿(英文)》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1689-x

摘要:

● Application of the MOF-composite membranes in adsorption was discussed.

关键词: Emerging organic contaminants     Metal organic frameworks     Synthesis     Adsorption     Catalysis    

Correction to: Highly degradable chitosan-montmorillonite (MMT) nanocomposite hydrogel for controlled

《环境科学与工程前沿(英文)》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1704-2

Nanocomposite materials in orthopedic applications

Mostafa R. Shirdar, Nasim Farajpour, Reza Shahbazian-Yassar, Tolou Shokuhfar

《化学科学与工程前沿(英文)》 2019年 第13卷 第1期   页码 1-13 doi: 10.1007/s11705-018-1764-1

摘要:

This chapter is an introduction to nanocomposite materials and its classifications with emphasis on orthopedic application. It covers different types of matrix nanocomposites including ceramics, metal, polymer and natural-based nanocomposites with the main features and applications in the orthopedic. In addition, it presents structure, composition, and biomechanical features of bone as a natural nanocomposite. Finally, it deliberately presents developing methods for nanocomposites bone grafting.

关键词: nanocomposite materials     orthopedic applications     bone grafting nanocomposites     nanocomposites classification    

Synthesis of vinasse-dolomite nanocomposite biochar via a novel developed functionalization method to

Nima Kamali, Abdollah Rashidi Mehrabadi, Maryam Mirabi, Mohammad Ali Zahed

《环境科学与工程前沿(英文)》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1249-6

摘要: Abstract • Nanocomposites were prepared by adding dolomite to vinasse at different ratio. • Textural and morphological features of adsorbents were studied in detail. • CCD based RSM was used for investigation of P ion removal by nanocomposite. • The qm based on Langmuir model for modified vinasse biochar was 178.57 mg/g. • P loaded nanocomposite improved plant growth and could be utilized as P-fertilizer. The effectiveness of phosphate (P) removal from aqueous solutions was investigated by novel low-cost biochars synthesized from vinasse and functionalized with calcined dolomite. The vinasse-derived biochar, synthesized via pyrolysis at different temperatures, showed easy preparation and a large surface area. The novel vinasse biochar nanocomposites were prepared by adding dolomite to the vinasse biochars with different weight percentages (10, 20 and 30%). The characteristics of the prepared materials were identified for further understanding of the inherent adsorption mechanism between P ions and vinasse biochars. Vinasse-dolomite nanocomposite was very effective in the adsorption of P species from aqueous media. The effect of the operational factors on Vinasse-dolomite nanocomposite was explored by applying response surface methodology (RSM). According to RSM results, the optimum condition was achieved to be contact time 90 (min), 250 (mg/L) of P concentration and pH 7. Thermodynamic isotherm and kinetic studies were applied on experimental data to understand the adsorption behavior. The Vinasse-dolomite nanocomposite revealed preferential P species adsorption in the presence of co-existing anions. The P species could be recovered by 1.0 M HCl where the efficiency was not affected up to the fifth cycle. The P-loaded Vinasse-dolomite nanocomposite was successfully tested on a plant; it significantly improved its growth and proved its potency as a P-based fertilizer substitute.

关键词: Biochar     Vinasse     Dolomite     Phosphate     Fertilizer    

Newly-modeled graphene-based ternary nanocomposite for the magnetophotocatalytic reduction of CO2 with

《化学科学与工程前沿(英文)》 2022年 第16卷 第10期   页码 1438-1459 doi: 10.1007/s11705-022-2166-y

摘要: The development of CO2 into hydrocarbon fuels has emerged as a green method that could help mitigate global warning. The novel structured photocatalyst is a promising material for use in a photocatalytic and magneto-electrochemical method that fosters the reduction of CO2 by suppressing the recombination of electron−hole pairs and effectively transferring the electrons to the surface for the chemical reaction of CO2 reduction. In our study, we have developed a novel-structured AgCuZnS2–graphene–TiO2 to analyze its catalytic activity toward the selective evolution of CO2. The selectivity of each nanocomposite substantially enhanced the activity of the AgCuZnS2–graphene–TiO2 ternary nanocomposite due to the successful interaction, and the selectivity of the final product was improved to a value 3 times higher than that of the pure AgCuZnS2 and 2 times higher than those of AgCuZnS2–graphene and AgCuZnS2–TiO2 under ultra-violet (UV)-light (λ = 254 nm) irradiation in the photocatalytic process. The electrochemical CO2 reduction test was also conducted to analyze the efficacy of the AgCuZnS2–graphene–TiO2 when used as a working electrode in laboratory electrochemical cells. The electrochemical process was conducted under different experimental conditions, such as various scan rates (mV·s–1), under UV-light and with a 0.07 T magnetic-core. The evolution of CO2 substantially improved under UV-light (λ = 254 nm) and with 0.07 T magnetic-core treatment; these improvements were attributed to the facts that the UV-light activated the electron-transfer pathway and the magnetic core controlled the pathway of electron-transmission/prevention to protect it from chaotic electron movement. Among all tested nanocomposites, AgCuZnS2–graphene–TiO2 absorbed the CO2 most strongly and showed the best ability to transfer the electron to reduce the CO2 to methanol. We believe that our newly-modeled ternary nanocomposite opens up new opportunities for the evolution of CO2 to methanol through an electrochemical and photocatalytic process.

关键词: ternary nanocomposite     photocatalytic     electrochemical CO2 reduction     UV-light     magnetic core    

Reduction kinetics of SrFeO/CaO∙MnO nanocomposite as effective oxygen carrier for chemical looping partial

《化学科学与工程前沿(英文)》 2022年 第16卷 第12期   页码 1726-1734 doi: 10.1007/s11705-022-2188-5

摘要: Chemical looping reforming of methane is a novel and effective approach to convert methane to syngas, in which oxygen transfer is achieved by a redox material. Although lots of efforts have been made to develop high-performance redox materials, a few studies have focused on the redox kinetics. In this work, the kinetics of SrFeO3−δ–CaO∙MnO nanocomposite reduction by methane was investigated both on a thermo-gravimetric analyzer and in a packed-bed microreactor. During the methane reduction, combustion occurs before the partial oxidation and there exists a transition between them. The weight loss due to combustion increases, but the transition region becomes less inconspicuous as the reduction temperature increased. The weight loss associated with the partial oxidation is much larger than that with combustion. The rate of weight loss related to the partial oxidation is well fitted by the Avrami–Erofeyev equation with n = 3 (A3 model) with an activation energy of 59.8 kJ∙mol‒1. The rate law for the partial oxidation includes a solid conversion term whose expression is given by the A3 model and a methane pressure-dependent term represented by a power law. The partial oxidation is half order with respect to methane pressure. The proposed rate law could well predict the reduction kinetics; thus, it may be used to design and/or analyze a chemical looping reforming reactor.

关键词: chemical looping reforming     SrFeO3−δ/CaO·MnO nanocomposite     reduction kinetics     Avrami–Erofeyev model     pressure-dependent term    

Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for

《环境科学与工程前沿(英文)》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1474-7

摘要:

• PA layer properties tune the primary nanochannels in MIL-101(Cr) TFN NF membranes.

关键词: Porous metal organic framework     Thin-film nanocomposite membrane     Primary selective nanochannels     Nanofiltration     Endocrine disrupting compounds    

Correlative investigation of copper/low-density polyethylene nanocomposite on the endometrial angiogenesis

LI Jianxiong, LIU Zilong, DUAN Yonggang, YU Jing, ZHU Changhong, LI Shuang, XIE Changsheng

《医学前沿(英文)》 2007年 第1卷 第4期   页码 401-404 doi: 10.1007/s11684-007-0078-3

摘要: The purpose of this study was to investigate the effects of copper/low-density polyethylene nanocomposite (nano-Cu/LDPE) on the endometrial angiogenesis in rats, and 100 sexual mature female SD rats were randomly divided into five groups: sham-operation groups (SO group, = 20), bulk copper groups (Cu group, = 20), LDPE groups ( = 20), nano-Cu/LDPE groups I ( = 20) and II ( = 20). The levels of angiopoietin-2 (Ang-2), its receptor (Tie-2) and CD34 of the rats endometria in each group were examined by using the S-P method of the immunohistochemistry 30 and 180 days after insertion, respectively. Compared with those in the SO group, the expression of Ang-2 and Tie-2 in all the experimental groups was obviously increased 30 days after insertion, and these parameters in nano-Cu/LDPE groups, except for Ang-2 level in nano-Cu/LDPE group II, were significantly lower in comparison with those in Cu group (<0.05). On the 180th day after insertion, Ang-2 and Tie-2 levels were still higher in Cu group and LDPE group, but there was no difference of Ang-2 and Tie-2 levels between nano-Cu/LDPE groups and the SO group (>0.05). Compared with those in the SO group, the significant increases in microvessel density (MVD) were observed on the 30th and the 180th day after the insertion of the bulk copper (<0.05). There was no significant difference in MVD counts before and after the insertion of nano-Cu/LDPE (>0.05). The results show that Nano-Cu/LDPE have slighter influence on the endometrial angiogenesis than bulk copper.

关键词: significant difference     female     endometrial angiogenesis     nano-Cu/LDPE     CD34    

Creep and recovery behaviors of magnetorheological elastomers

Weihua LI, Yang ZHOU, Tongfei TIAN, Gursel ALICI,

《机械工程前沿(英文)》 2010年 第5卷 第3期   页码 341-346 doi: 10.1007/s11465-010-0096-8

摘要: This paper presents experimental and modeling study of creep and recovery behaviors of magneto-rheological elastomers (MREs) under constant stresses. Experimental study was accomplished using a rheometer with parallel-plate geometry. Under constant stresses ranging from a small value to a large one, the resultant strains were recorded. The experimental results demonstrated that MREs behave as linear visocleastic properties. The effects of the magnetic field and stress on MRE creep behaviors were discussed. Moreover, a four-parameter viscoelastic model was developed to describe MRE creep behaviors. The comparison between the experimental results and the modeling predictions indicates that the model can predict MRE creep behaviors very well.

关键词: magneto-rheological elastomers (MREs)     creep     recovery     linear viscoelastic model    

Erratum to: Synthesis of vinasse-dolomite nanocomposite biochar via a novel developed functionalization

《环境科学与工程前沿(英文)》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1387-5

标题 作者 时间 类型 操作

Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic

期刊论文

Preparation and characterization of ZnO/ZnS hybrid photocatalysts via microwave-hydrothermal method

ZHAO Jinglian, WANG Xinping, ZHAO Liang

期刊论文

Vibration control of a structure using Magneto-Rheological grease damper

Shinya SUGIYAMA, Tomoki SAKURAI, Shin MORISHITA

期刊论文

Effect of magneto rheological damper on tool vibration during hard turning

P. Sam PAUL, A. S. VARADARAJAN

期刊论文

Polymer nanocomposites for microactuation and magneto-electric transduction

Kaori YUSE, Benoit GUIFFARD, Rabah BELOUADAH, Lionel PETIT, Laurence SEVEYRAT, Daniel GUYOMAR

期刊论文

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

期刊论文

Correction to: Highly degradable chitosan-montmorillonite (MMT) nanocomposite hydrogel for controlled

期刊论文

Nanocomposite materials in orthopedic applications

Mostafa R. Shirdar, Nasim Farajpour, Reza Shahbazian-Yassar, Tolou Shokuhfar

期刊论文

Synthesis of vinasse-dolomite nanocomposite biochar via a novel developed functionalization method to

Nima Kamali, Abdollah Rashidi Mehrabadi, Maryam Mirabi, Mohammad Ali Zahed

期刊论文

Newly-modeled graphene-based ternary nanocomposite for the magnetophotocatalytic reduction of CO2 with

期刊论文

Reduction kinetics of SrFeO/CaO∙MnO nanocomposite as effective oxygen carrier for chemical looping partial

期刊论文

Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for

期刊论文

Correlative investigation of copper/low-density polyethylene nanocomposite on the endometrial angiogenesis

LI Jianxiong, LIU Zilong, DUAN Yonggang, YU Jing, ZHU Changhong, LI Shuang, XIE Changsheng

期刊论文

Creep and recovery behaviors of magnetorheological elastomers

Weihua LI, Yang ZHOU, Tongfei TIAN, Gursel ALICI,

期刊论文

Erratum to: Synthesis of vinasse-dolomite nanocomposite biochar via a novel developed functionalization

期刊论文